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課程名稱 |
高等無機化學專論二
DISCUSSION IN ADVANCED INORGANIC CHEMISTRY (II) |
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開課學期 |
98-2 |
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授課對象 |
理學院 化學所化學組 |
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授課教師 |
王 瑜 |
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課號 |
Chem8030 |
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課程識別碼 |
223 D1420 |
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班次 |
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學分 |
3 |
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全/半年 |
半年 |
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必/選修 |
必修 |
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上課時間 |
星期二2(9:10~10:00)星期四3,4(10:20~12:10) |
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上課地點 |
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備註 |
本課程中文授課,使用英文教科書。上課教室：新504教室。與林英智合開
限博士班 且 限本系所學生(含輔系、雙修生)
總人數上限：30人 |
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Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/982adv_inorg |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
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課程大綱
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為確保您我的權利,請尊重智慧財產權及不得非法影印
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課程概述 |
課程內容主要介紹近代無機化學研究過程中﹐所使用的各種物理方法。首先介紹群論、分子軌域與光譜學之基本原理。其次將較深入的探討應用在無機化學上的各種光譜技術：包括可見光-紫外光光譜、紅外光光譜、核磁共振光譜、電子順磁共振光譜、磁性量測。隨後介紹Ｘ光繞射等應用於化學晶體結構之常用分析技術。 |
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課程目標 |
將無機化學中的各項光譜分析技術，介紹給學生了解，並希冀學生能善加利用於研究上。 |
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課程要求 |
本課程以化學研究所碩、博士生為授課對象，為無機化學組學生之必修課程之一
先修課程：無機化學 |
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預期每週課後學習時數 |
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Office Hours |
另約時間 |
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指定閱讀 |
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參考書目 |
<1>Drago, “Physical Methods for Chemists” 2nd Ed.
<2>Glusker and Trueblood, “Crystal Structure Analysis, A Primer” 2nd Ed.
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評量方式
(僅供參考) |
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No. |
項目 |
百分比 |
說明 |
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1. |
期中考試 |
50% |
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2. |
期末考試 |
50% |
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週次 |
日期 |
單元主題 |
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第1週 |
2/23,2/25 |
Chapter 7, 8, 9 and 11 of the Text Book
I.Nuclear Magnetic Resonance
Introduction: Behavior of a bar magnet in a magnetic field, rotating axis system, magnetization vectors and relaxation, the NMR transition, the Bloch equation. The quantum mechanical description of the NMR experiment, Relaxation effects and mechanism and spin-spin splitting, Dynamic: Evaluation of thermodynamic data with NMR kinetics and Fourier transform NMR, Multipluse methods. |
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第2週 |
3/02,3/04 |
I.Nuclear Magnetic Resonance
Introduction: Behavior of a bar magnet in a magnetic field, rotating axis system, magnetization vectors and relaxation, the NMR transition, the Bloch equation. The quantum mechanical description of the NMR experiment, Relaxation effects and mechanism and spin-spin splitting, Dynamic: Evaluation of thermodynamic data with NMR kinetics and Fourier transform NMR, Multipluse methods. |
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第3週 |
3/09,3/11 |
I.Nuclear Magnetic Resonance
Introduction: Behavior of a bar magnet in a magnetic field, rotating axis system, magnetization vectors and relaxation, the NMR transition, the Bloch equation. The quantum mechanical description of the NMR experiment, Relaxation effects and mechanism and spin-spin splitting, Dynamic: Evaluation of thermodynamic data with NMR kinetics and Fourier transform NMR, Multipluse methods. |
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第4週 |
3/16,3/18 |
Chapter 7, 8, 9 and 11 of the Text Book
II.Electron Magnetic (Spin) Resonance
Introduction, Nuclear hyperfine splitting, hydrogen atom, presentation of the spectrum, hyperfine splitting in isotropic systems involving more than one nucleus, Anisotropic effect, anisotropy in g value, anisotropy in the hyperfine coupling |
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第5週 |
3/23,3/25 |
II.Electron Magnetic (Spin) Resonance
Introduction, Nuclear hyperfine splitting, hydrogen atom, presentation of the spectrum, hyperfine splitting in isotropic systems involving more than one nucleus, Anisotropic effect, anisotropy in g value, anisotropy in the hyperfine coupling |
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第6週 |
3/30,4/01 |
II.Electron Magnetic (Spin) Resonance
Introduction, Nuclear hyperfine splitting, hydrogen atom, presentation of the spectrum, hyperfine splitting in isotropic systems involving more than one nucleus, Anisotropic effect, anisotropy in g value, anisotropy in the hyperfine coupling |
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第7週 |
4/06,4/08 |
Chapter 7, 8, 9 and 11 of the Text Book
III.Magnetic Properties
Introduction, types of magnetic behavior, Van Vleck’s equation, application of susceptibility measurements. |
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第8週 |
4/13,4/15 |
III.Magnetic Properties
Introduction, types of magnetic behavior, Van Vleck’s equation, application of susceptibility measurements. |
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第9週 |
4/20,4/22 |
期中考週 |
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第10週 |
4/27,4/29 |
X-ray Absorption Spectroscopy --- XANES |
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第11週 |
5/04,5/06 |
X-ray Absorption Spectroscopy --- XANES, EXAFS |
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第12週 |
5/11,5/13 |
EXAFS, L-edge |
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第13週 |
5/18,5/20 |
L-edge, XMCD |
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第14週 |
5/25,5/27 |
XRD |
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第15週 |
6/01,6/03 |
XRD |
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第16週 |
6/08,6/10 |
XRD |
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第17週 |
6/15,6/17 |
Magnetism |
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第18週 |
6/22,6/25 |
期末考週 |
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